SELF-HEATING LIQUID, TOXIC, INORGANIC, N.O.S. These substances are the most liable to spontaneous combustion; and 2 Self-heating substances, which are substances, other than pyrophoric substances, which, in contact with air without energy supply, are liable to self-heating. For some (Type A) materials and packages, a transport index is calculated on the basis of the maximum dose rate on the external surface of the packaging, and different labels and regulations apply depening on this index. Some have already burnt out; others still emit smoke and sulphurous fumes from the crevices in the hillsides, and through the fissures may be seen the glowing coal and rock. These substances are classified as either pyrophoric substances or self-heating substances. Subscribe now using PayPal, or ARTICLES CONTAINING A SUBSTANCE LIABLE TO SPONTANEOUS COMBUSTION, N.O.S. Burning of firecrackers. Please consult International Associations and Local Authorities for more details and latest information. These, substances will ignite only in large amounts (kilograms) and after long periods of time (hours. Class 6 Division 6.1 Toxic Substances Packing Group. For instance, strike-anywhere-matches (UN 1331) would be classified as a Class 4.1 substance. Q.3. Substances are divided into different packing groups according to the degree of danger they present to transportation. Division 4.2 - Substances liable to spontaneous combustion. Class 4.2, "Substances liable to spontaneous combustion", EU General Data Protection Regulation (GDPR), our article about the different ADR-classes. SODIUM SULPHIDE, ANHYDROUS or SODIUM SULPHIDE with less than 30% water of crystallization, SEED CAKE with more than 1.5% oil and not more than 11% moisture, CALCIUM, PYROPHORIC or CALCIUM ALLOYS, PYROPHORIC, CALCIUM DITHIONITE (CALCIUM HYDROSULPHITE), POTASSIUM DITHIONITE (POTASSIUM HYDROSULPHITE). Gaining of ignition temperature of the combustible substance. 1.1.3.2 - Exemptions related to the carriage of gases, 1.1.3.6 - Exemptions related to quantities carried per transport unit, 1.1.4 - Applicability of other regulations, 1.1.4.2 - Carriage in a transport chain including maritime or air carriage, 1.2 - DEFINITIONS AND UNITS OF MEASUREMENT, 1.3 - TRAINING OF PERSONS INVOLVED IN THE CARRIAGE OF DANGEROUS GOODS, 1.4 - SAFETY OBLIGATIONS OF THE PARTICIPANTS, 1.6.2 - Pressure receptacles and receptacles for Class 2, 1.6.3 - Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles, 1.6.4 - Tank-containers, portable tanks and MEGCs, 1.6.6.2 - Packages approved under the 1973, 1973 (as amended), 1985 and 1985 (as amended 1990) editions of IAEA Safety Series No. with oil, IRON OXIDE, SPENT or IRON SPONGE, SPENT obtained from coal gas purification, METAL CATALYST, WETTED with a visible excess of liquid, PAPER, UNSATURATED OIL TREATED, incompletely dried (including carbon paper), PHOSPHORUS, WHITE or YELLOW, UNDER WATER or IN SOLUTION, POTASSIUM SULPHIDE, ANHYDROUS or POTASSIUM SULPHIDE with less than 30% water of crystallization. form explosive mixtures with air, and articles containing such substances. SELF-HEATING LIQUID, CORROSIVE, ORGANIC, N.O.S. Solids which, under conditions encountered in transport, are readily combustible or may cause or contribute to fire through friction; self-reactive substances (solids and liquids) and polymerizing substances which are liable to undergo a strongly exothermic reaction; solid desensitized explosives which may explode if not diluted sufficiently; Class 4.2 Substances liable to spontaneous combustion A remarkable case of spontaneous ignition occurred a few years ago in England. Many translated example sentences containing "substances liable to spontaneous combustion" - German-English dictionary and search engine for German translations. To learn more about combustion, read . When the oxidation of a sensitive material (e.g., phosphorus) by oxygen in the atmosphere reaches the material's autoignition temperature. Combustion: You may have noticed that some materials such as paper burn easily, while materials such as iron do not. Download this Class 4 Flammable Solids Substances Liable To Spontaneous Combustion 3170 vector illustration now. Class 6.2, infectious substances, covers substances which are known or are reasonably expected to contain pathogens, i.e. It works completely offline and provides much more advanced functions than the website. It works completely offline and provides much more advanced functions than the website. Class 4.2, "Substances liable to spontaneous combustion" For a comprehensive description of each class, see our article about the different ADR-classes . School The University of Sydney; Course Title AC PUAFIR303; Uploaded By BailiffBook96636. substance feature substance intoxication substance liable to cause infection substance liable to spontaneous combustion substance number substance of a crime substance of a testimony substance of abuse substance of an offence substance of anthropogenic origin substance of the alleged offence substance of the case substance of the matter Dangerous goods - All substances of an inflammable nature which are liable to spontaneous combustion either in themselves or when stowed next to other substances and, when mixed with air, are liable to generate explosive gases or produce suffocation or poisoning or tainting of foodstuffs. If the goods have multiple dangerous propreties, the most dominant one determines the class to which it shall belong. 3255 tert-BUTYL HYPOCHLORITE; and, - Self-heating solids, oxidizing, assigned to UN No. We noticed that you're enjoying our website - great! A substance meeting the criteria of Class 8 Corrosive Material having an inhalation toxicity of dusts and mists (LC50) in the range of Packing Group I, but toxicity through oral ingestion or dermal contact only (not inhalation) in the range of Packing Group III or less must be classified as Class 8 Corrosive Material. CLASS 4 - Flammable Solids, Substances liable to spontaneous combustion; Substances that on contact with water emit flammable gases (water-reactive substances) 4.1 A solid that under normal conditions of transport is readily combustible, or would cause or contribute to fire through friction or from heat retained from manufacturing or processing . according to iata's dangerous goods regulations (dgr) manual, "dangerous goods (also known as hazardous materials or hazmat) are articles or substances which are capable of posing a hazard to health, safety, property or the environment and which are shown in the list of dangerous goods in the iata dangerous goods regulations or which are Class 4 is divided into three division as follow: Disclaimer: this information is provided for convenience only. Ans: Combustion can be classified into several categories based on the amount of energy required and the reaction's byproducts. substances liable to spontaneous combustion; SUBSTANCES WHICH, IN CONTACT WITH WATER, EMIT FLAMMABLE GASES 4.1 In IMDG Code, class 4 deals with substances, other than those classified as explosives, which, under conditions of transport, are readily combustible or may cause or contribute to a fire. Class 6 - Toxic* substances and Infectious substances . Jrgen F. Brune, in Advances in Productive, Safe, and Responsible Coal Mining, 2019 6.7.3 Prevention of spontaneous combustion. There are five different forms of combustion- complete combustion, incomplete combustion, rapid combustion, spontaneous combustion, and explosion. entries of Class 4.2 shall be based on the results of the test, procedures in accordance with the Manual of Tests and Criteria, Part III, section 33.3; experience shall. In some mining districts the coal is liable to spontaneous combustion. . Flammable solids, substances liable to spontaneous combustion, substances which, in contact with water, emit flammable gases, Class 4 - Flammable solids, substances liable to spontaneous combustion, substances which, in contact with water, emit flammable gases. They are described as substances liable to spontaneous combustion (pyrophoric substances); EurLex-2 Liquid organic spontaneously combustible toxic substances , and solutions of organic spontaneously combustible toxic substances (such as preparations and wastes) which cannot be classified under other collective headings: Class 4: Flammable Solids; Substances Liable to Spontaneous Combustion; Substances That, on Contact with Water, Emit Flammable Gases (Water-Reactive Substances) Divisions. Substances and articles which, during carraige, present a danger not covered by any of the other classes fall under class 9. 1. The shipper is responsible for properly classifying material prior to offering it into . It can occur because of a chemical reaction or because of a sensitive substance reacting with air or water. Following are the examples of Combustion: Combustion of petrol or diesel in a car engine to run a car. You can find more information in our Terms and conditions, where you can also revoke your consent at any time. If the product that you are storing is classified as either class 4.2 or 4.3 flammable solids and listed in the . 2. It begins with a slow oxidation process (as atmospheric oxidation or bacterial fermentation) under conditions not permitting . A pyrotechnic substance (or mixture) is designed to produce an effect by heat, light, sound, gas or smoke or a combination of these as the result of non-detonative, self-sustaining, exothermic chemical reactions. SELF-HEATING LIQUID, CORROSIVE, INORGANIC, N.O.S. Fresh pistachios, if stacked under pressure, can burst into flames and cause a cargo fire. Pyrophoric substances: These include solutions and mixtures (liquid or solid) that, even in small quantities, ignite within 5 minutes of coming in contact with air. This website uses cookies in order to provide the best user experience. ZIRCONIUM, DRY, finished sheets, strip or coiled wire, MANEB or MANEB PREPARATION with not less than 60% maneb, SEED CAKE with not more than 1.5% oil and not more than 11% moisture, SODIUM HYDROSULPHIDE with less than 25% water of crystallization, TITANIUM TRICHLORIDE, PYROPHORIC or TITANIUM TRICHLORIDE MIXTURE, PYROPHORIC, FERROUS METAL BORINGS, SHAVINGS, TURNINGS or CUTTINGS in a form liable to self- heating, 9-PHOSPHABICYCLO-NONANES (CYCLOOCTADIENE PHOSPHINES). CLASS 4 - Flammable solids; substances liable to spontaneous combustion; substances which, in contact with water, emit flammable gases Class 4.1 Solids having the properties of being easily ignited by external sources, such as spark and flames, and of being readily combustible, or of being liable to cause or contribute to a fire or cause one . They all have in common that they are flammable under certain conditions. The classes are part of the United Nations-based system of identifying dangerous goods, and are used within many different subsystems such as the ADR, RID, IMDG and DGR for classifying dangerous goods and hazardous materials. Oxidizing substances and organic peroxides, Miscellaneous dangerous substances and articles, EU General Data Protection Regulation (GDPR), Class 1 - Explosive substances and articles, Class 5 - Oxidizing substances and organic peroxides, Class 6 - Toxic and infectious substances, Class 9 - Miscellaneous dangerous substances and articles, Flammable solids, self-reactive substances, polymerizing substances and solid desensitized explosives, Substances liable to spontaneous combustion, Substances which, in contact with water, emit flammable gases, Corrosive substances which, in contact with water, emit flammable gases, Corrosive substances, toxic and articles containing such substances, Corrosive substances, flammable, liquid, toxic. - Pyrophoric substances which are substances, including mixtures and solutions (liquid or solid), which even in small quantities ignite on contact with air within five minutes. Examples: . temperature to over 160 C is observed within 24 hours. 4.1.1.20 - Use of salvage pressure receptacles, 4.1.1.21 - Verification of the chemical compatibility of plastics packagings, including IBCs, by assimilation of filling substances to standard liquids, 4.1.2 - Additional general provisions for the use of IBCs, 4.1.3 - General provisions concerning packing instructions, 4.1.3.6 - Pressure receptacles for liquids and solids, 4.1.3.8 - Unpackaged articles other than Class 1 articles, 4.1.4.1 - Packing instructions concerning the use of packagings (except IBCs and large packagings), 4.1.4.2 - Packing instructions concerning the use of IBCs, 4.1.4.3 - Packing instructions concerning the use of large packagings, 4.1.5 - Special packing provisions for goods of Class 1, 4.1.6 - Special packing provisions for goods of Class 2 and goods of other classes assigned to packing instruction P200, 4.1.7 - Special packing provisions for organic peroxides (Class 5.2) and self-reactive substances of Class 4.1, 4.1.7.1 - Use of packagings (except IBCs), 4.1.7.2 - Use of intermediate bulk containers, 4.1.8 - Special packing provisions for infectious substances (Class 6.2), 4.1.9 - Special packing provisions for radioactive material, 4.1.9.2 - Requirements and controls for carriage of LSA material and SCO, 4.1.10 - Special provisions for mixed packing, 4.2 - USE OF PORTABLE TANKS AND UN MULTIPLE-ELEMENT GAS CONTAINERS (MEGCs), 4.2.1 - General provisions for the use of portable tanks for the carriage of substances of Class 1 and Classes 3 to 9, 4.2.1.10 - Additional provisions applicable to the carriage of Class 3 substances in portable tanks, 4.2.1.11 - Additional provisions applicable to the carriage of Classes 4.1, 4.2 or 4.3 substances (other than Class 4.1 self-reactive substances) in portable tanks, 4.2.1.12 - Additional provisions applicable to the carriage of Class 5.1 substances in portable tanks, 4.2.1.13 - Additional provisions applicable to the carriage of Class 5.2 substances and Class 4.1 self-reactive substances in portable tanks, 4.2.1.14 - Additional provisions applicable to the carriage of Class 6.1 substances in portable tanks, 4.2.1.15 - Additional provisions applicable to the carriage of Class 6.2 substances in portable tanks, 4.2.1.16 - Additional provisions applicable to the carriage of Class 7 substances in portable tanks, 4.2.1.17 - Additional provisions applicable to the carriage of Class 8 substances in portable tanks, 4.2.1.18 - Additional provisions applicable to the carriage of Class 9 substances in portable tanks, 4.2.1.19 - Additional provisions applicable to the carriage of solid substances carried above their melting point, 4.2.2 - General provisions for the use of portable tanks for the carriage of non-refrigerated liquefied gases and chemicals under pressure, 4.2.3 - General provisions for the use of portable tanks for the carriage of refrigerated liquefied gases, 4.2.4 - General provisions for the use of UN multiple-element gas containers (MEGCs), 4.2.5 - Portable tank instructions and special provisions, 4.2.5.2.5 - Determination of the appropriate portable tank instructions, 4.2.5.3 - Portable tank special provisions, 4.3 - USE OF FIXED TANKS (TANK-VEHICLES), DEMOUNTABLE TANKS, TANK-CONTAINERS AND TANK SWAP BODIES WITH SHELLS MADE OF METALLIC MATERIALS, AND BATTERY-VEHICLES AND MULTIPLE-ELEMENT GAS CONTAINERS (MEGCs), 4.3.2 - Provisions applicable to all classes, 4.3.2.4 - Empty tanks, battery-vehicles and MEGCs, uncleaned, 4.3.3 - Special provisions applicable to Class 2, 4.3.3.2 - Filling conditions and test pressures, 4.3.4 - Special provisions applicable to Classes 1 and 3 to 9, 4.3.4.1 - Coding, rationalized approach and hierarchy of tanks, 4.4 - USE OF FIBRE-REINFORCED PLASTICS (FRP) TANKS, FIXED TANKS (TANK-VEHICLES), DEMOUNTABLE TANKS, TANK-CONTAINERS AND TANK SWAP BODIES, 4.7 - USE OF MOBILE EXPLOSIVES MANUFACTURING UNITS (MEMUs), 5.1.1 - Application and general provisions, 5.1.3 - Empty uncleaned packagings (including IBCs and large packagings), tanks, MEMUs, vehicles and containers for carriage in bulk, 5.1.5.1 - Approval of shipments and notificat, 5.1.5.2 - Certificates issued by the competent authority, 5.1.5.3 - Determination of transport index (TI) and criticality safety index (CSI), 5.1.5.4 - Specific provisions for excepted packages of radioactive material of Class 7, 5.1.5.5 - Summary of approval and prior notification requirements, 5.2.1.5 - Additional provisions for goods of Class 1, 5.2.1.6 - Additional provisions for goods of Class 2, 5.2.1.7 - Special marking provisions for radioactive material, 5.2.1.8 - Special marking provisions for environmentally hazardous substances, 5.2.2.1.11 - Special provisions for the labelling of radioactive material, 5.3 - PLACARDING AND MARKING OF CONTAINERS, MEGCs, MEMUs, TANKCONTAINERS, PORTABLE TANKS AND VEHICLES, 5.3.1.2 - Placarding of containers, MEGCs, tank-containers and portable tanks, 5.3.1.3 - Placarding of vehicles carrying containers, MEGCs, tank-containers or portable tanks, 5.3.1.4 - Placarding of vehicles for carriage in bulk, tank-vehicles, battery-vehicles, MEMUs and vehicles with demountable tanks, 5.3.1.5 - Placarding of vehicles carrying packages only, 5.3.1.6 - Placarding of empty tank-vehicles, battery-vehicles, MEGCs, MEMUs, tank-containers, portable tanks and empty vehicles and containers for carriage in bulk, 5.3.2.1 - General orange-coloured plate marking provisions, 5.3.2.2 - Specifications for the orange-coloured plates, 5.3.2.2.3 - Example of orange-coloured plate with hazard identification number and UN number, 5.3.2.3 - Meaning of hazard identification numbers, 5.3.3 - Elevated temperature substance mark, 5.3.6 - Environmentally hazardous substance mark, 5.4.1 - Dangerous goods transport document and related information, 5.4.1.1 - General information required in the transport document, 5.4.1.1.6 - Special provision for empty means of containment, uncleaned, 5.4.1.2 - Additional or special information required for certain classes, 5.4.1.2.3 - Additional provisions for self-reactive substances and polymerizing substances of Class 4.1 and organic peroxides of Class 5.2, 5.4.1.2.5 - Additional provisions for Class 7, 5.4.2 - Container/vehicle packing certificate, 5.4.4 - Retention of dangerous goods transport information, 5.4.5 - Example of a multimodal dangerous goods form, 5.5.2 - Special provisions applicable to fumigated cargo transport units (UN 3359), 5.5.3 - Special provisions applicable to packages and vehicles and containers containing substances presenting a risk of asphyxiation when used for cooling or conditioning purposes (such as dry ice (UN 1845) or nitrogen, refrigerated liquid (UN 1977) or argon, refrigerated liquid (UN 1951)), 5.5.3.3 - Packages containing a coolant or conditioner, 5.5.3.4 - Marking of packages containing a coolant or conditioner, 5.5.3.5 - Vehicles and containers containing unpackaged dry ice, 5.5.3.6 - Marking of vehicles and containers, 6 - Requirements for the construction and testing of packagings, intermediate bulk containers (IBCs), large packagings, tanks and bulk containers, 6.1 - REQUIREMENTS FOR THE CONSTRUCTION AND TESTING OF PACKAGINGS, 6.1.2 - Code for designating types of packagings, 6.1.3.11 - Examples for marking NEW packagings, 6.1.3.12 - Examples for marking RECONDITIONED packagings, 6.1.3.13 - Example for marking SALVAGE packagings, 6.1.4.14 - Steel, aluminium or other metal boxes, 6.1.4.19 - Composite packagings (plastics material), 6.1.4.20 - Composite packagings (glass, porcelain or stoneware), 6.1.5.1 - Performance and frequency of tests, 6.1.5.2 - Preparation of packagings for testing, 6.1.5.3.6 - Criteria for passing the test, 6.1.5.5 - Internal pressure (hydraulic) test, 6.1.5.7 - Supplementary permeability test for plastics drums and jerricans in accordance with 6.1.4.8 and for composite packagings (plastics material) in accordance with 6.1.4.19 intended for the carriage of liquids having a flash-point 60 C, other than 6HA1 packagings, 6.1.6 - Standard liquids for verifying the chemical compatibility testing of polyethylene packagings, including IBCs, in accordance with 6.1.5.2.6 and 6.5.6.3.5, respectively, 6.2 - REQUIREMENTS FOR THE CONSTRUCTION AND TESTING OF PRESSURE RECEPTACLES, AEROSOL DISPENSERS, SMALL RECEPTACLES CONTAINING GAS (GAS CARTRIDGES) AND FUEL CELL CARTRIDGES CONTAINING LIQUEFIED FLAMMABLE GAS, 6.2.1.3.6 - Additional requirements for closed cryogenic receptacles, 6.2.1.4 - Approval of pressure receptacles, 6.2.1.8 - Requirements for inspection bodies, 6.2.2 - Requirements for UN pressure receptacles, 6.2.2.1 - Design, construction and initial inspection and test, 6.2.2.5 - Conformity assessment system and approval for manufacture of pressure receptacles, 6.2.2.5.3 - Manufacturer's quality system, 6.2.2.6 - Approval system for periodic inspection and test of pressure receptacles, 6.2.2.6.3 - Quality system and audit of the periodic inspection and test body, 6.2.2.6.4 - Approval process for periodic inspection and test bodies, 6.2.2.8 - Marking of non-refillable UN pressure receptacles, 6.2.2.9 - Marking of UN metal hydride storage systems, 6.2.2.10 - Marking of UN bundles of cylinders, 6.2.2.11 - Equivalent procedures for conformity assessment and periodic inspection and test, 6.2.3 - General requirements for non-UN pressure receptacles, 6.2.3.6 - Approval of pressure receptacles, 6.2.3.8 - Requirements for inspection bodies, 6.2.3.9 - Marking of refillable pressure receptacles, 6.2.3.9.7 - Marking of bundles of cylinders, 6.2.3.10 - Marking of non-refillable pressure receptacles, 6.2.4 - Requirements for non-UN pressure receptacles designed, constructed and tested according to referenced standards, 6.2.5 - Requirements for non-UN pressure receptacles not designed, constructed and tested according to referenced standards, 6.2.5.3 - Metal cylinders, tubes, pressure drums and bundles of cylinders, 6.2.5.4 - Additional provisions relating to aluminium-alloy pressure receptacles for compressed gases, liquefied gases, dissolved gases and non pressurized gases subject to special requirements (gas samples) as well as articles containing gas under pressure other than aerosol dispensers and small receptacles containing gas (gas cartridges), 6.2.5.5 - Pressure receptacles in composite materials, 6.2.6 - General requirements for aerosol dispensers, small receptacles containing gas (gas cartridges) and fuel cell cartridges containing liquefied flammable gas, 6.2.6.3.2.3 - Gas cartridges and fuel cell cartridges, 6.3 - REQUIREMENTS FOR THE CONSTRUCTION AND TESTING OF PACKAGINGS FOR CLASS 6.2 INFECTIOUS SUBSTANCES OF CATEGORY A, 6.3.3 - Code for designating types of packagings, 6.3.5.1 - Performance and frequency of tests, 6.3.5.2 - Preparation of packagings for testing, 6.3.5.3.6 - Special preparation of test sample for the drop test, 6.4 - REQUIREMENTS FOR THE CONSTRUCTION, TESTING AND APPROVAL OF PACKAGES FOR RADIOACTIVE MATERIAL AND FOR THE APPROVAL OF SUCH MATERIAL, 6.4.4 - Requirements for excepted packages, 6.4.5 - Requirements for Industrial packages, 6.4.5.4 - Alternative requirements for Types IP-2 and IP-3 packages, 6.4.6 - Requirements for packages containing uranium hexafluoride, 6.4.8 - Requirements for Type B(U) packages, 6.4.9 - Requirements for Type B(M) packages, 6.4.10 - Requirements for Type C packages, 6.4.11 - Requirements for packages containing fissile material, 6.4.12 - Test procedures and demonstration of compliance, 6.4.13 - Testing the integrity of the containment system and shielding and evaluating criticality safety, 6.4.15 - Tests for demonstrating ability to withstand normal conditions of carriage, 6.4.16 - Additional tests for Type A packages designed for liquids and gases, 6.4.17 - Tests for demonstrating ability to withstand accident conditions in carriage, 6.4.18 - Enhanced water immersion test for Type B(U) and Type B(M) packages containing more than 10^5 A2 and Type C packages, 6.4.19 - Water leakage test for packages containing fissile material, 6.4.21 - Inspections for packagings designed to contain 0.1 kg or more of uranium hexafluoride, 6.4.22 - Approvals of package designs and materials, 6.4.23 - Applications and approvals for radioactive material carriage, 6.5 - REQUIREMENTS FOR THE CONSTRUCTION AND TESTING OF INTERMEDIATE BULK CONTAINERS (IBCs), 6.5.1.4 - Designatory code system for IBCs, 6.5.2.4 - Marking of remanufactured composite IBCs (31HZ1), 6.5.4 - Testing, certification and inspection, 6.5.5.1 - Specific requirements for metal IBCs, 6.5.5.2 - Specific requirements for flexible IBCs, 6.5.5.3 - Specific requirements for rigid plastics IBCs, 6.5.5.4 - Specific requirements for composite IBCs with plastics inner receptacles, 6.5.5.5 - Specific requirements for fibreboard IBCs, 6.5.5.6 - Specific requirements for wooden IBCs, 6.5.6.1 - Performance and frequency of tests, 6.5.6.3 - Preparation of IBCs for testing, 6.5.6.3.7 - Design type tests required and sequential order, 6.5.6.8 - Internal pressure (hydraulic) test, 6.6 - REQUIREMENTS FOR THE CONSTRUCTION AND TESTING OF LARGE PACKAGINGS, 6.6.2 - Code for designating types of large packagings, 6.6.4 - Specific requirements for large packagings, 6.6.4.1 - Specific requirements for metal large packagings, 6.6.4.2 - Specific requirements for flexible material large packagings, 6.6.4.3 - Specific requirements for plastics large packagings, 6.6.4.4 - Specific requirements for fibreboard large packagings, 6.6.4.5 - Specific requirements for wooden large packagings, 6.6.5 - Test requirements for large packagings, 6.6.5.1 - Performance and frequency of test, 6.6.5.3.4.5 - Criteria for passing the test, 6.7 - REQUIREMENTS FOR THE DESIGN, CONSTRUCTION, INSPECTION AND TESTING OF PORTABLE TANKS AND UN MULTIPLE-ELEMENT GAS CONTAINERS (MEGCs), 6.7.1 - Application and general requirements, 6.7.2 - Requirements for the design, construction, inspection and testing of portable tanks intended for the carriage of substances of Class 1 and Classes 3 to 9, 6.7.2.2 - General design and construction requirements, 6.7.2.9 - Setting of pressure-relief devices, 6.7.2.12 - Capacity of pressure-relief devices, 6.7.2.13 - Marking of pressure-relief devices, 6.7.2.14 - Connections to pressure-relief devices, 6.7.2.15 - Siting of pressure-relief devices, 6.7.2.17 - Portable tank supports, frameworks, lifting and tie-down attachments, 6.7.3 - Requirements for the design, construction, inspection and testing of portable tanks intended for the carriage of non-refrigerated liquefied gases, 6.7.3.2 - General design and construction requirements, 6.7.3.9 - Marking of pressure-relief devices, 6.7.3.10 - Connections to pressure-relief devices, 6.7.3.11 - Siting of pressure-relief devices, 6.7.3.13 - Portable tank supports, frameworks, lifting and tie-down attachments, 6.7.4 - Requirements for the design, construction, inspection and testing of portable tanks intended for the carriage of refrigerated liquefied gases, 6.7.4.2 - General design and construction requirements, 6.7.4.7 - Capacity and setting of pressure-relief devices, 6.7.4.8 - Marking of pressure-relief devices, 6.7.4.9 - Connections to pressure-relief devices, 6.7.4.10 - Siting of pressure-relief devices, 6.7.4.12 - Portable tank supports, frameworks, lifting and tie-down attachments, 6.7.5 - Requirements for the design, construction, inspection and testing of UN multiple-element gas containers (MEGCs) intended for the carriage of non-refrigerated gases, 6.7.5.2 - General design and construction requirements, 6.7.5.5 - Capacity of pressure relief devices, 6.7.5.6 - Marking of pressure-relief devices, 6.7.5.7 - Connections to pressure-relief devices, 6.7.5.8 - Siting of pressure-relief devices, 6.7.5.10 - MEGC supports, frameworks, lifting and tie-down attachments, 6.8 - REQUIREMENTS FOR THE CONSTRUCTION, EQUIPMENT, TYPE APPROVAL, INSPECTIONS AND TESTS, AND MARKING OF FIXED TANKS (TANK-VEHICLES), DEMOUNTABLE TANKS AND TANK-CONTAINERS AND TANK SWAP BODIES, WITH SHELLS MADE OF METALLIC MATERIALS, AND BATTERY-VEHICLES AND MULTIPLE ELEMENT GAS CONTAINERS (MEGCs), 6.8.2 - Requirements applicable to all classes, 6.8.2.6 - Requirements for tanks which are designed, constructed and tested according to referenced standards, 6.8.3 - Special requirements applicable to Class 2, 6.8.5 - Requirements concerning the materials and construction of fixed welded tanks, demountable welded tanks, and welded shells of tank-containers for which a test pressure of not less than 1 MPa (10 bar) is required, and of fixed welded tanks, demountable welded tanks and welded shells of tank-containers intended for the carriage of refrigerated liquefied gases of Class 2, 6.9 - REQUIREMENTS FOR THE DESIGN, CONSTRUCTION, EQUIPMENT, TYPE APPROVAL, TESTING AND MARKING OF FIBRE-REINFORCED PLASTICS (FRP) FIXED TANKS (TANK-VEHICLES), DEMOUNTABLE TANKS, TANK-CONTAINERS AND TANK SWAP BODIES, 6.9.2.14 - Special requirements for the carriage of substances with a flash-point of not more than 60 C, 6.10 - REQUIREMENTS FOR THE CONSTRUCTION, EQUIPMENT, TYPE APPROVAL, INSPECTION AND MARKING OF VACUUM-OPERATED WASTE TANKS, 6.11 - REQUIREMENTS FOR THE DESIGN, CONSTRUCTION, INSPECTION AND TESTING OF BULK CONTAINERS, 6.11.2 - Application and general requirements, 6.11.3 - Requirements for the design, construction, inspection and testing of containers conforming to the CSC used as BK1 or BK2 bulk containers, 6.11.3.1 - Design and construction requirements, 6.11.4 - Requirements for the design, construction and approval of BK1 or BK2 bulk containers other than containers conforming to the CSC, 6.11.5 - Requirements for the design, construction, inspection and testing of BK3 flexible bulk containers, 6.11.5.1 - Design and construction requirements, 6.11.5.2 - Service equipment and handling devices, 6.12 - REQUIREMENTS FOR THE CONSTRUCTION, EQUIPMENT, TYPE APPROVAL, INSPECTIONS AND TESTS, AND MARKING OF TANKS, BULK CONTAINERS AND SPECIAL COMPARTMENTS FOR EXPLOSIVES OF MOBILE EXPLOSIVES MANUFACTURING UNITS (MEMUs), 6.12.3.1 - Tanks with a capacity of 1 000 litres or more, 6.12.3.2 - Tanks with a capacity of less than 1 000 litres, 6.12.5 - Special compartments for explosives, 7 - Provisions concerning the conditions of carriage, loading, unloading and handling, 7.2 - PROVISIONS CONCERNING CARRIAGE IN PACKAGES, 7.3 - PROVISIONS CONCERNING CARRIAGE IN BULK, 7.3.2 - Provisions for the carriage in bulk when the provisions of 7.3.1.1 (a) are applied, 7.3.2.10 - Use of flexible bulk containers, 7.3.3 - Provisions for carriage in bulk when the provisions of 7.3.1.1 (b) are applied, 7.4 - PROVISIONS CONCERNING CARRIAGE IN TANKS, 7.5 - PROVISIONS CONCERNING LOADING, UNLOADING AND HANDLING, 7.5.1 - General provisions concerning loading, unloading and handling, 7.5.4 - Precautions with respect to foodstuffs, other articles of consumption and animal feeds, 7.5.5 - Limitation of the quantities carried, 7.5.5.2 - Limitations with respect to explosive substances and articles, 7.5.7.6 - Loading of flexible bulk containers, 7.5.10 - Precautions against electrostatic charges, 7.5.11 - Additional provisions applicable to certain classes or specific goods, 8 - Requirements for vehicle crews, equipment, operation and documentation, 8.1 - GENERAL REQUIREMENTS CONCERNING TRANSPORT UNITS AND EQUIPMENT ON BOARD, 8.1.2 - Documents to be carried on the transport unit, 8.1.5 - Miscellaneous equipment and equipment for personal protection, 8.2 - REQUIREMENTS CONCERNING THE TRAINING OF THE VEHICLE CREW, 8.2.1 - Scope and general requirements concerning the training of drivers, 8.2.2 - Special requirements concerning the training of drivers, 8.2.2.7.1 - Examinations for the basic training course, 8.2.2.8 - Certificate of driver's training, 8.2.3 - Training of persons other than the drivers holding a certificate in accordance with 8.2.1, involved in the carriage of dangerous goods by road, 8.3 - MISCELLANEOUS REQUIREMENTS TO BE COMPLIED WITH BY THE VEHICLE CREW, 8.3.6 - Use of the parking brakes and wheel chocks, 8.3.7 - Use of the parking brakes and wheel chocks, 8.4 - REQUIREMENTS CONCERNING THE SUPERVISION OF VEHICLES, 8.5 - ADDITIONAL REQUIREMENTS RELATING TO PARTICULAR CLASSES OR SUBSTANCES, 8.6 - ROAD TUNNEL RESTRICTIONS FOR THE PASSAGE OF VEHICLES CARRYING DANGEROUS GOODS, 8.6.2 - Road signs or signals governing the passage of vehicles carrying dangerous goods, 8.6.4 - Restrictions for the passage of transport units carrying dangerous goods through tunnels, 9 - Requirements concerning the construction and approval of vehicles, 9.1 - SCOPE, DEFINITIONS AND REQUIREMENTS FOR THE APPROVAL OF VEHICLES, 9.1.2 - Approval of EX/II, EX/III, FL and AT vehicles and MEMUs, 9.1.2.2 - Requirements for type-approved vehicles, 9.1.3.5 - Model for certificate of approval for vehicles carrying certain dangerous goods, 9.2 - REQUIREMENTS CONCERNING THE CONSTRUCTION OF VEHICLES, 9.2.1 - Compliance with the requirements of this Chapter, 9.2.2.6 - Electrical connections between motor vehicles and trailers, 9.2.6 - Coupling devices of motor vehicles and trailers, 9.2.7 - Prevention of other risks caused by fuels, 9.3 - ADDITIONAL REQUIREMENTS CONCERNING COMPLETE OR COMPLETED EX/II OR EX/III VEHICLES INTENDED FOR THE CARRIAGE OF EXPLOSIVE SUBSTANCES AND ARTICLES (CLASS 1) IN PACKAGES, 9.3.1 - Materials to be used in the construction of vehicle bodies, 9.3.6 - External heat sources and load compartment, 9.4 - ADDITIONAL REQUIREMENTS CONCERNING THE CONSTRUCTION OF THE BODIES OF COMPLETE OR COMPLETED VEHICLES INTENDED FOR THE CARRIAGE OF DANGEROUS GOODS IN PACKAGES (OTHER THAN EX/II AND EX/III VEHICLES), 9.5 - ADDITIONAL REQUIREMENTS CONCERNING THE CONSTRUCTION OF THE BODIES OF COMPLETE OR COMPLETED VEHICLES INTENDED FOR THE CARRIAGE OF DANGEROUS SOLIDS IN BULK, 9.6 - ADDITIONAL REQUIREMENTS CONCERNING COMPLETE OR COMPLETED VEHICLES INTENDED FOR THE CARRIAGE OF TEMPERATURE CONTROLLED SUBSTANCES, 9.7 - ADDITIONAL REQUIREMENTS CONCERNING FIXED TANKS (TANK-VEHICLES), BATTERY-VEHICLES AND COMPLETE OR COMPLETED VEHICLES USED FOR THE CARRIAGE OF DANGEROUS GOODS IN DEMOUNTABLE TANKS WITH A CAPACITY GREATER THAN 1 M3 OR IN TANKCONTAINERS, PORTABLE TANKS OR MEGCs OF A CAPACITY GREATER THAN 3 M3 (EX/III, FL AND AT VEHICLES), 9.7.9 - Additional safety requirements concerning EX/III vehicles, 9.8 - ADDITIONAL REQUIREMENTS CONCERNING COMPLETE AND COMPLETED MEMUs, 9.8.2 - Requirements concerning tanks and bulk containers. 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